Synthesis and properties of a Cu(II) complexing pyrazole ligandoside in DNA.
نویسندگان
چکیده
The development of metal base pairs is of immense importance for the construction of DNA nanostructures. Here we report the synthesis of a biaryl pyrazole-phenol nucleoside that forms in DNA a stable self-pair upon complexation of a Cu(II) ion. A sequence with five consecutive pyrazole nucleotides allows the complexation of five Cu(II) ions in a row.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 4 شماره
صفحات -
تاریخ انتشار 2014